Argentometric titration. Definition: The process of determining the quantity of a sample by adding measured increments of a titrant until the end-point, at which. automatic titrator will be used to perform the titration, and to obtain the titration curve. Background. Argentometric Titrations. In order for a titrimetric method to be . A titration in which Ag+ is the titrant is called an argentometric titration. Table provides a list of several typical precipitation titrations.

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Calculate pCl after the equivalence point by first calculating the concentration of excess AgNO 3 and then calculating the concentration of Cl — using the K sp for AgCl. As we learned earlier, the calculations are straightforward. Anionic dyes such as dichlorofluorescein are attracted to the particles, and undergo a colour change upon adsorption, representing the end-point.

9.5: Precipitation Titrations

Calculate the titration curve for the titration of These methods are based on back titration of excess silver with standardized thiocyanate argentomettric.

Calculate pCl before the equivalence point by determining the concentration of unreacted NaCl. Quantitative Calculations The quantitative relationship between the titrand and the titrant gitrations determined by the stoichiometry of the titration reaction.

Waylander 5, 1 10 Chemistry Stack Exchange works best with JavaScript enabled. Chloride ions react with silver I ions to give the insoluble silver chloride:.

What are some example of the use of argentometric titration? Ferric acetate removes phosphates.

Argentometric (silver nitrate) titrations overview

By using our site, you acknowledge that you have read and understand our Cookie PolicyPrivacy Policyand our Terms of Service. The red points corresponds to the data in Table 9. As a result, the end point is always later than the equivalence point.


Sign up using Email and Password. The first type of indicator is a ttrations that forms a precipitate with the titrant. Email Required, but never shown. The quantitative relationship between the titrand and the titrant is determined by the stoichiometry of the titration argento,etric.

For example, after adding Precipitation titrations also can be extended to the analysis of mixtures provided that there is a significant difference in the solubilities of the precipitates. Thus far we have examined titrimetric methods based on acid—base, complexation, and redox reactions. Prior to the end-point of the titration, chloride ions remain in excess.

Precipitation Titrations – Chemistry LibreTexts

Typically, it is used to determine the amount of chloride present in a sample. Additional results for the titration curve are shown in Table 9. By now you are familiar with our approach to calculating a titration curve.

Sign up or log in Sign up using Google. What about argentometric titration? Home Questions Tags Users Unanswered. A reaction in which the analyte and titrant form an insoluble precipitate also can titrstions as the basis for a titration. We call this type of titration a precipitation titration. A typical calculation is shown in the following example.

Argentometry – Wikipedia

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David Harvey DePauw University. The red arrows show the end points. Chloride ions react with silver I ions to give the insoluble silver chloride: Post as a guest Name.


Solution There are two precipitates in this analysis: Like, we use alkalimetric titration to calculate the real concentration of table vinegar. This page was last edited on 5 Decemberat To calculate the concentration of Cl — we use the K sp expression for AgCl; thus. Views Read Edit View history. A simple equation takes advantage of the fact that the sample contains only KCl and NaBr; thus. By clicking “Post Your Answer”, you acknowledge that you have read our updated terms of serviceprivacy policy and cookie policyand that your continued use of the website is subject to these policies.

As we have done with other titrations, we first show how to calculate the titration curve and then demonstrate how we can quickly sketch a reasonable approximation of the titration curve. The analysis for I — using the Volhard method requires a back titration. Click here to review your answer to this exercise. An example of a lab procedure is here 2. The concentration of unreacted Cl — after adding Eosin tetrabromofluorescein is suitable for titrating against bromideiodideand thiocyanate anions, giving a sharper end-point than dichlorofluorescein.

The first reagent is added in excess and the second reagent used to back titrate the excess. Quantitative chemical analysis 6th ed.